Trace moisture detection using continuous-wave cavity ring-down spectroscopy.

نویسندگان

  • John B Dudek
  • Peter B Tarsa
  • Armando Velasquez
  • Mark Wladyslawski
  • Paul Rabinowitz
  • Kevin K Lehmann
چکیده

We have developed an instrument to measure trace concentrations of small hydride species in gases using continuous-wave cavity ring-down spectroscopy with near-infrared diode laser excitation. An rms baseline equivalent absorbance of 9.2 x 10(-11) cm(-1)/square root(n) is found, where n is the number of ring-down transients. When the 1396.376-nm absorption line of water is used, this corresponds to a noise equivalent moisture concentration in nitrogen gas of 68 pptv/square root(n). Water vapor concentration is detected over a range extending from 3 to 1000 ppbv and found to depend linearly on the concentration as determined by a calibrated commercial moisture sensor.

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عنوان ژورنال:
  • Analytical chemistry

دوره 75 17  شماره 

صفحات  -

تاریخ انتشار 2003